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The solubility of MgO in molten MgCl 2 and CaCl 2 has been studied. In pure MgCl 2 , the MgO solubility was determined to be 0.63-2.90 mol5 at 1073-1373 K, while 0.24-0.63 mol% in pure CaCl 2 at 1223-1523 K. The effects ofMgCl 2 and CaO addition to CaCl 2 were investigated, and the solubility product of MgO was found to increase with the amount of MgCl 2 addition, while CaO addition did not affect significantly. They were explained in terms of the activity coefficient of oxide ion (O 2 - ) as well as the enthalpy of mixing for the MgO-CaCl 2 system. From the experimental results, the corrosion possibility of MgO refractory by Cl-containing gas was considered.

The Solubility of MgO in Molten MgCl<SUB>2</SUB>-CaCl<SUB>2</SUB> Salt