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Orientation relationship formations at early stage of the solidification and rodlamella transition for unidirectionally solidified Al2O3/LnAlO3 eutectic system were examined. Al2O3 was the first phase to nucleate in the Al2O3/LnAlO3 eutectic microstructure. In the case of Al2O3 phase nucleated as the primary phase, firstly some specific orientation to the solidification direction for Al2O3 phase were constructed and then the orientation to the solidification direction for LnAlO3 phase were gradually fix to some specific directions. The microstructures for Ln=Sm and Nd showed irregularity lamella and rod type, respectively.

nippon kinzoku gakkaishi/nihon kinzoku gakkaishi

Microstructures and Orientation Relationship Formation and Rod-Lamella Transition in a Uni-directionally Solidified Al&lt;SUB&gt;2&lt;/SUB&gt;O&lt;SUB&gt;3&lt;/SUB&gt;/LnAlO&lt;SUB&gt;3&lt;/SUB&gt;(Ln=La, Nd, Sm, Gd) Eutectic System