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Formulations incorporating benzophenone oligodimethacrylate (BP-DMA) and   graphene structures (graphene oxide/GO, reduced graphene oxide/RGO) were   exposed to UV/vis irradiation or femtosecond laser beam to achieve hybrid   composites. All structures were characterized through various methods   including 1H NMR and FTIR spectroscopies, optical microscopy, TEM, SEM/EDAX   analysis, and DSC/XRD techniques. The photopolymerization of BP-DMA in   monomer compositions with and without GO or RGO was investigated by photo-DSC   and FTIR methods for determining the polymerization kinetic parameters. The   photopolymerization experiments revealed a good photoreactivity of the   monomers (degree of conversion: 65-77%) after 1 minute exposure to UV/vis   irradiation and the addition of graphene (up to 0.5%), whereas the   polymerization rate varied between 0.14 and 0.1 s-1. Moreover, two-photon   photopolymerization of the formulations in presence/absence of GO or RGO   nanosheets (0.1 wt.%) generated 2D microstructures by direct laser writing   procedure. Also, the morphology and the properties of composites materials   were analyzed

Polymer-graphene composites by photocuring of a system containing benzophenone macromer