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A novel method combining a traditional immersion precipitation process for   making membranes with photopolymerization and crosslinking of functional   monomers included in the casting solution was used to prepare asymmetric   polyethersulfone membranes with submicron particles incorporating glycidyl   methacrylate copolymer. In order to introduce sulfonic groups epoxide rings   of glycidyl methacrylate were opened using two methods. The first method was   functionalization with sodium sulfite, and the second method was   functionalization with sulfuric acid and then grafting with   2-acrylamido-2-methylpropane sulfonic acid. Obtained membranes were   characterized using infrared spectroscopy, conductometric titration and water   permeability measurements. Scanning electron microscopy and atomic force   microscopy were used to investigate the surface morphology and topology of   membrane. Dynamic adsorption of Rhodamine B as a model dye was used to   demonstrate suitability of these novel membranes for membrane adsorption   since the adsorption capacity for dye cations was much better for both   functionalized membrane with sodium sulfite and grafted membrane with   2-acrylamido-2-methylpropane sulfonic acid compared to the nonfunctionalized   membrane. [Projekat Ministarstva nauke Republike Srbije, br. TR32008 and III   43009

Novel negatively-charged membrane adsorbers made using combination of photopolymerization and immersion precipitation