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Densities data of n-hexane, toluene and dichloromethane at temperatures   288.15-413.15 K and at pressures 0.1-60 MPa, determined in our previous work,   were fitted to the modified Tait equation of state. The fitted   temperature-pressure dependent density data were used to calculate the   derived properties: the isothermal compressibility, the isobaric thermal   expansivity, the difference between specific heat capacity at constant   pressure and at constant volume and the internal pressure, over the entire   temperature and pressure intervals specified above. In order to assess the   proposed modeling procedure, a comparison of the obtained values for the   isothermal compressibility and the isobaric thermal expansivity with the   corresponding literature data were performed. The average absolute percentage   deviations for isothermal compressibility were: for n-hexane 2.01-3.64%, for   toluene 0.64-2.48% and for dichloromethane 1.81-3.20%; for the isobaric   thermal expansivity: for n-hexane 1.31-4.17%, for toluene 0.71-2.45% and for   dichloromethane 1.16-1.61%. By comparing the obtained deviations values with   those found in the literature it can be concluded that the presented results   agree good with the literature data. [Projekat Ministarstva nauke Republike   Srbije, br. 172063

journal of the serbian chemical society

Modeling of density and calculations of derived volumetric properties for n-hexane, toluene and dichloromethane at pressures 0.1-60 MPa and temperatures 288.15-413.15 K