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Low abundance of lithium in Earth’s crust and its high participation in   overall cost of lithium-ion batteries incited intensive investigation of   sodium-ion batteries, in hope that they may become similar in basic   characteristics: specific energy and specific power. Furthermore, over the   last years the research has been focused on the replacement of organic   electrolytes of Li- and Na-ion batteries, by aqueous electrolytes, in order   to simplify the production and improve safety of use. In this lecture, some   recent results on the selected intercalation materials are presented: layered   structure vanadium oxides, olivine and nasicon phosphates, potentially usable   in both Li and Na aqueous rechargeable batteries. After their   characterization by X-ray diffraction and electron microscopy, the   electrochemical behavior was studied by both cyclic voltammetry and   hronopotenciometry. By comparing intercalation kinetics and coulombic   capacity of these materials in LiNO3 and NaNO3 solutions, it was shown that   the following ones: Na1.2V3O8, Na2V6O16/C , NaFePO4/C and NaTi2(PO4)3/C may   be used as electrode materials in aqueous alkali-ion batteries

Comparison of lithium and sodium intercalation materials