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The processes of Pb electrodeposition in the diffusion control were examined   by the scanning electron microscopic (SEM) analysis of the formed crystals.   Orientation of grains of hexagonal shape formed in the initial stage of   electrodeposition strongly affected the final morphology of Pb crystals.   Formation of Pb crystals of the different shape from the same initial shape   was discussed by the effect of orientation of initially formed grains on the   type of diffusion control. The spherical diffusion layer was formed around   the tip of the hexagonal shaped grain oriented by the tip towards the bulk of   solution leading to formation of elongated crystals in the growth process. On   the other hand, the cylindrical type of diffusion was responsible for growth   of hexagonal shaped grains oriented by the lateral side towards the bulk of   solution. Pb crystals with well defined sides parallel to the surface area of   macroelectrode were formed by this type of diffusion. [{Projekat Ministarstva   nauke Republike Srbije, br. 172046: Electrochemical synthesis and   characterization of nanostructured functional materials for application in   new technologies

Effect of orientation of initially formed grains on the final morphology of electrodeposited lead