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The synthesis and structural characterization of a square-planar copper(II)   complex with pyridoxal S-methylisothiosemicarbazone (PLITSC) of the formula   [Cu(PLITSC−H)H2O]Br•H2O (1) as the first Cu(II) complex with monoanionic   form of this ligand were described. Complex 1 together with two previously   synthesized complexes [Cu(PLITSC)Br2] (2) and [Cu(PLITSC)Br(MeOH)]Br (3)   were characterized by elemental analysis, IR and electronic spectra and also   by the methods of thermal analysis, conductometry and magnetochemistry.   [Projekat Pokrajisnkog sekretarijata za nauku i tehnoloski razvoj Vojvodine   i Ministarstva nauke Republike Srbije, br. 172014

journal of the serbian chemical society

Transition metal complexes with thiosemicarbazide-based ligands. Part 60. Reactions of copper(II) bromide with pyridoxal S-methylisothiosemicarbazone (PLITSC). Crystal structure of [Cu(PLITSC−H)H2O]Br•H2O