Open AccessTransition metal complexes with thiosemicarbazide-based ligands. Part 60. Reactions of copper(II) bromide with pyridoxal S-methylisothiosemicarbazone (PLITSC). Crystal structure of [Cu(PLITSC−H)H2O]Br•H2O
Author(s) -
Vukadin M. Leovac,
Ljiljana S. VojinovićJešić,
Sonja A. Ivković,
Marko V. Rodić,
Ljiljana S. Jovanović,
Berta Barta Holló,
Katalin Mészáros Szécsényi
Publication year - 2013
Publication title -
journal of the serbian chemical society
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.227
H-Index - 45
eISSN - 1820-7421
pISSN - 0352-5139
DOI - 10.2298/jsc130622084l
Subject(s) - magnetochemistry , chemistry , copper , oxamide , transition metal , metal , pyridoxal , crystal structure , ligand (biochemistry) , conductometry , bromide , inorganic chemistry , crystallography , thermal analysis , organic chemistry , thermal , catalysis , meteorology , biochemistry , physics , receptor , phosphate
The synthesis and structural characterization of a square-planar copper(II) complex with pyridoxal S-methylisothiosemicarbazone (PLITSC) of the formula [Cu(PLITSC−H)H2O]Br•H2O (1) as the first Cu(II) complex with monoanionic form of this ligand were described. Complex 1 together with two previously synthesized complexes [Cu(PLITSC)Br2] (2) and [Cu(PLITSC)Br(MeOH)]Br (3) were characterized by elemental analysis, IR and electronic spectra and also by the methods of thermal analysis, conductometry and magnetochemistry. [Projekat Pokrajisnkog sekretarijata za nauku i tehnoloski razvoj Vojvodine i Ministarstva nauke Republike Srbije, br. 172014
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