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A phosphomolybdic acid catalysed novel method for the synthesis of 1,2-dihydro-1-aryl-3H-naphth(1,2-e)(1,3)oxazin-3-one derivatives by a one-pot, three-component reaction of β-naphthol, aromatic aldehydes and urea in excel- lent yields is described.

An environmentally benign one-pot synthesis of 1,2-dihydro-1-arylnaphtho[1,2-e][1,3]oxazine-3-one derivatives catalysed by phosphomolybdic acid