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Mn(II) and Co(II) complexes having the general composition (M(L)2X2) (where L = 2-pyridinecarboxaldehyde thiosemicarbazone, M = Mn(II) and Co(II), X = Cl - and - 3 NO ) were synthesized. All the metal complexes were characterized by elemental analysis, molar conductance, magnetic susceptibi- lity measurements, mass, IR, EPR, electronic spectral studies and thermogravi- metric analysis (TG). Based on the spectral studies, an octahedral geometry was assigned for all the complexes. Thermal studies of the compounds suggest that the complexes are more stable than the free ligand. This fact was supported by the kinetic parameters calculated using the Horowitz-Metzger (H-M) and Coats-Redfern (C-R) equations. The antibacterial properties of the ligand and its metal complexes were also examined and it was observed that the com- plexes are more potent bactericides than the free ligand.

Spectroscopic, thermal and antibacterial studies on Mn(II) and Co(II) complexes derived from thiosemicarbazone