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We report on the detailed NMR spectral analyses of amino- or/and   hydroxy-substituted benzoic acids: anthranilic (AA), 3-hydroxyanthranilic   (3-HAA), 5-hydroxyanthranilic (5-HAA), salicylic (SA), 4-aminosalicylic   (4-ASA) and 5-aminosalicylic (5-ASA) acids. According to a literature survey,   there are limited, unassigned or even incorrectly assigned spectral data to   these benzoic acid derivatives. In order to amend the situation, a complete   assignment of 1H- and 13C-NMR spectra of these compounds, recorded in   perdeuteriodimethyl sulfoxide (DMSO-d6), based on a combination of 1D- and   2D-NMR experiments, including 1H-1H COSY, NOESY, HSQC and HMBC, was   performed. [Projekat Ministarstva nauke Republike Srbije, br. 172061

Complete assignment of 1H- and 13C-NMR spectra of anthranilic acid and its hydroxy derivatives and salicylic acid and its amino derivatives