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The removal of endocrine disrupting compounds (EDCs) from aqueous environment was proposed using magnetic molecularly imprinted polymer (M-MIP) particles. Estrogen imprinted MIP layer was coated on magnetic core by ultrasonication assisted synthesis. The resultant particles exhibit satisfactory binding property and strong magnetic response. 17(3-estradiol bisphenol A imprinted M-MIP offers a promising alternative for a class-specific adsorption of EDCs. A comparative study implies that magnetic separation has advantages over centrifugation and membrane filtration, facilitating an efficient, cost-effective separation of M-MIP from aqueous matrices. Environmental variables (ionic strength, humic acid, pH and temperature) have minor effects on M-MIP adsorption performance, showing its suitability to real water streams. The M-MIP possesses good stability and regenerating potential reusable for at least seven times without significant deterioration in recognition and magnetic properties. The simultaneous removal of EDCs was verified using river water samples spiked with five representative steroid and phenolic EDCs at a trace (10 ^g/L) concentration level.

Development of magnetic molecularly imprinted polymer nanoparticles for rapid and selective removal of endocrine disrupting compounds from aqueous environment