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Heterobimetallic complexes (Cu(NC-Cy-CN)2)(Au(C6F5)2)·0.5 Toluene (1) and (Cu(NC-Cy- CN)2)(Au(C6F5)2)·CH2Cl2 (2) and (AuCu(C6F5)2(NC-Cy-CN)2)·CH2Cl2 (3) (with the same stoichiometry but different structure) have been synthesized and the crystal structure of complex 2·CH2Cl2 has been characterized through X-ray dif- fraction studies. The structure shows a cationic (Cu(NC-Cy-CN)2) + polymer that runs parallel to the crystallographic y axis, which is formed by the copper centers and the nitrile bridging ligands, and (Au(C6F5)2) - anions that link the polym- eric chain via non-classical C-H···Au hydrogen bonds. Complexes 1, 2 and 3 only differ in the solvents and the time used for their synthesis but this greatly affects their photophysical properties. Complexes 1, 2 and 3 are brightly luminescent in solid state at room temperature with lifetimes in the microseconds range. Complexes 1 and 2 display emissions arising from IL transitions while for complex 3 an emission arising from a MLCT is proposed.

Solvent Induced Luminescence in Supramolecular Heterobimetallic Gold(I)-Copper(I) Complexes with a Bidentate Nitrile Ligand