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A review focused on recent advances in intramolecular aza-Wittig reaction of phosphazenes with several car- bonyl or analogous compounds is reported. Phosphazenes afford intramolecular aza-Wittig reaction with different groups within the molecule as aldehydes, ketones, esters, thioesters, amides, anhydrides and sulfimides. One of the most impor- tant applications of this reaction is the synthesis of a wide range of heterocyclic compounds, ranging from simple mono- cyclic compounds to complex polycyclic and macrocyclic systems.

Synthetic Applications of Intramolecular Aza-Wittig Reaction for the Preparation of Heterocyclic Compounds