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The objective of this project is to develop the scientific basis for hydrothermal separation of chromium from High Level Waste (HLW) sludges. Our worked is aimed at attaining a fundamental understanding of chromium speciation, oxidation/reduction and dissolution kinetics, reaction mechanisms, and transport properties under hydrothermal conditions in both simple and complex salt solutions that will ultimately lead to an efficient chromium leaching process

Enhanced Sludge Processing of HLW: Hydrothermal Oxidation of Chromium, Technetium, and Complexants by Nitrate