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Hydrogen-powered polymer electrolyte membrane (PEM) fiel cells, fueled by on-board H2 generation from liquid fiels, represent a potential enabling technology for future vehicles. Much currenteffort has been devoted to the use of stem reforming or partial oxidation of liquid fuels for on-board H2generation,but these technologies generatelarge amounts of CO, which can poison PEM fiel cells. The purpose of this project was to develop a catalytic membrane reactor system for the generation of pure H2 via selective dehydrogenation of liquid fiels. Separation of hydrogen from hydrocarbons was to be achieved by modification of commercial asymmetric aluminamembrane tubes with permselective microporous ceramic membranes. Hydrous titanium oxide (HTO) and silica-doped hydrous titanium oxide (HTO:Si) ion exchange materialswere evaluatedas a component of the microporous ceramic composite membrane material and as a support for bulk dehydrogenation catalysts,

Hydrogen Production for Fuel Cells by Selective Dehydrogenation of Alkanes in Catalytic Membrane Reactors