English (United Kingdom)

https://curated-unify.zendy.io/wp-json/zendy-region/v1/featured_content/oa?rat=en

https://curated-unify.zendy.io/wp-json/zendy-region/v1/highlighted_journal/

Global: Zendy Plus annual

Presents the access of premium content as premium feature

Premium Content

Presents the keyphrase highlighting as premium feature

Keyphrase Highlighting

Presents the summarisation as premium feature

Summarisation

Insights

Presents the pdf analysis as premium feature

PDF Analysis

Presents the zaia usage as premium feature

ZAIA

Global: Zendy Plus monthly

Global: Zendy Tools annual

Global: Zendy Tools monthly

Global: Zendy Free Plan

Witzkeite, ideally Na 4 K 4 Ca(NO 3 ) 2 (SO 4 ) 4 ·2H 2 O, is a new mineral found in the oxidation zone of the guano mining field at Punta de Lobos, Tarapacá region, Chile. It occurs as colorless, tabular crystals up to 140 μm in length, associated with dittmanite and nitratine. Witzkeite is colorless and transparent, with a white streak and a vitreous luster. It is brittle, with Mohs hardness 2 and distinct cleavage on {001}. Measured density is 2.40(2) g/cm 3 , calculated density is 2.403 g/cm 3 . Witzkeite is biaxial (-) with refractive indexes α = 1.470(5), β = 1.495(5), γ = 1.510(5), measured 2V = 50-70°. The empirical composition is (electron microprobe, mean of five analyses, H 2 O, CO 2 , and N 2 O 5  by gas chromatography; wt%): Na 2 O 12.83, K 2 O 22.64, CaO 7.57, FeO 0.44, SO 3  39.96, N 2 O 5  12.7, H 2 O 4.5, total 100.64; CO 2  was not detected. The chemical formula, calculated based on 24 O, is: Na 3.40 K 3.95 Ca 1.11 Fe 0.05 (NO 3 ) 1.93 (SO 4 ) 4.10 (H 4.10 O 1.81 ). Witzkeite is monoclinic, space group C2/c, with unit-cell parameters: a = 24.902(2), b = 5.3323(4), c = 17.246(1) Å, β = 94.281(7)°, V = 2283.6(3) Å 3  (Z = 4). The crystal structure was solved using single-crystal X-ray diffraction data and refined to R 1 (F) = 0.043. Witzkeite belongs to a new structure type and is noteworthy for the very rare simultaneous presence of sulfate and nitrate groups. The eight strongest X-ray powder-diffraction lines [d in Å (I in %) (h k l)] are: 12.38 (100) (2 0 0), 4.13 (19) (6 0 0), 3.10 (24) (8 0 0), 2.99 (7) (8̄ 0 2), 2.85 (6) (8 0 2), 2.69 (9) (7̅ 1 3), 2.48 (12) (10 0 0), and 2.07 (54) (12 0 0). The IR spectrum of witzkeite was collected in the range 390-4000 cm -1 . The spectrum shows the typical bands of SO 4  2-  ions (1192, 1154, 1116, 1101, 1084, 993, 634, and 617 cm -1 ) and of NO 3  -  ions (1385, 1354, 830, 716, and 2775 cm -1 ). Moreover, a complex pattern of bands related to H 2 O is visible (bands at 3565, 3419, 3260, 2405, 2110, 1638, and 499 cm -1 ). The IR spectrum is discussed in detail.

Witzkeite: A new rare nitrate-sulphate mineral from a guano deposit at Punta de Lobos, Chile