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Reactions involving the  VI Ti IV Al- VI Al IV Si exchange in muscovite, biotite, and hornblende were calibrated thermodynamically using a set of experimental and natural data in rutile- plus quartz/ coesite-bearing assemblages. The specific respective reactions are

Titanium in muscovite, biotite, and hornblende: Modeling, thermometry, and rutile activities of metapelites and amphibolites