English (United Kingdom)

https://curated-unify.zendy.io/wp-json/zendy-region/v1/featured_content/oa?rat=en

https://curated-unify.zendy.io/wp-json/zendy-region/v1/highlighted_journal/

Global: Zendy Plus annual

Presents the access of premium content as premium feature

Premium Content

Presents the keyphrase highlighting as premium feature

Keyphrase Highlighting

Presents the summarisation as premium feature

Summarisation

Insights

Presents the pdf analysis as premium feature

PDF Analysis

Presents the zaia usage as premium feature

ZAIA

Global: Zendy Tools annual

Global: Zendy Free Plan

Global: Zendy Tools monthly

Global: Zendy Plus monthly

Droplets of an iron-bearing calcia magnesia aluminosilicate (Fe-CMAS) melt were reacted under distinctly reducing conditions (f O₂  = 2.4 × 10 -13  and 6.4 × 10 -15  atm) at high temperature (~1400 °C) and ambient pressure. The low f O₂  environment was maintained by a flowing gas mixture of CO and CO 2 , with a high content of CO. Molten metallic iron alloyed with silicon and carbon formed on the surface of the melt; no metal was observed in sample interiors. A color change from brown to pale blue confined to the outer layer of the melt indicated that essentially complete reduction of Fe 3+  to Fe 2+  had occurred in this region. Analysis of the reaction kinetics, particularly in comparison to melts of similar polymerization but free of CaO, reveals that the concentration of electron holes has decreased to such an extent that ionic transport in the melt is significantly slowed and the diffusion of CO as a neutral species becomes dominant and rate-limiting: molecular CO, initially incorporated into the melt as a physically dissolved species, subsequently reacts to form chemically dissolved (bonded into the melt structure) CO 3  2-  anions, consuming electron holes in the process. The chemical diffusion coefficient for CO in the reduced melt at 1400 °C is estimated as D CO  ≈ 4 × 10 -4  cm 2 /s, consistent with that of other, similarly sized molecular species (e.g., H 2  and H 2 O) for similarly polymerized melts, as reported by other investigators. Upon quenching, the droplet acts as a closed system. Internal redox couples see the reduction of the carbonate so as to form bubbles of CO, the composition of which are confirmed with Raman spectroscopy. The open-system reduction and closed-system quenching dynamics are analyzed following an Ellingham-diagram approach.

Mechanism and kinetics of reduction of a FeO-Fe 2 O 3 -CaO-MgO aluminosilicate melt in a high-CO-activity environment