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Solubility and solution mechanism(s) of reduced (N+H)- and H-containing N-O-H volatile components in Na 2 O-SiO 2  composition melts in equilibrium with NH 3 +H 2 +N 2  and H 2 O+H 2  fluid and H- and N-isotope concentrations in these melts were determined experimentally at 1.5 GPa and 1400 °C as a function of hydrogen fugacity, f H₂ , and melt polymerization (composition), NBO/Si (NBO/Si = 0.4-1.18). This NBO/Si-range is similar to that between dacite and olivine tholeiite melt (NBO/Si ~0.4-1). The f H ₂ was controlled between that of the iron-wüstite + H 2 O [log f H₂ (IW) ~3.42 (bar)] and that of the magnetite-hematite + H 2 O [log f H₂ (MH) ~ -0.91 (bar)] buffer.

american mineralogist

Nitrogen and hydrogen isotope compositions and solubility in silicate melts in equilibrium with reduced (N+H)-bearing fluids at high pressure and temperature: Effects of melt structure