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The solubility and solution mechanisms of nitrogen in silicate melts have been examined via nitrogen analyses and vibrational spectroscopy (Raman and FTIR). Pressure (P), temperature (T), hydrogen fugacity (f H₂ ), and silicate melt composition (degree of melt polymerization) were independent variables in experiments in the 1-2.5 GPa pressure and 1300-1500 °C temperature ranges. The f H₂  was controlled at values defined by the magnetite-hematite (MH), Mn 3 O 4 -MnO (MM), NiO-Ni (NNO), magnetite-wustite (MW), and iron-wustite (IW) buffers together with H 2 O.

american mineralogist

Amorphous materials: Properties, structure, and durability: Solubility and solution mechanisms of NOH volatiles in silicate melts at high pressure and temperature—amine groups and hydrogen fugacity