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Based on powder X-ray diffraction (pXRD) measurements of many mica solid solution series of synthetic powder samples (between Mg, Co, Ni, and Fe end-members, with different degrees of oxidation, vacancy, and Al/Si contents, and including an OH/F substitution series; 75 samples indexed as 1M polytype, space group C2/m) and on 175 previously published structural refinements of 1M micas (refined in space group C2/m) comprising 37 synthetic and 138 natural single-crystal samples, we show that the relation

american mineralogist

Fundamental difference between synthetic powder and natural or synthetic single-crystal 1M micas: Geometric homo-octahedral vs. geometric meso-octahedral sheets