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The solubility of CO 2  in hydrous basaltic andesite was examined in  f  O 2  -controlled experiments at a temperature of 1125 °C and pressures between 310–1200 MPa. Concentrations of dissolved H 2 O and CO 2  in experimental glasses were determined by ion microprobe calibrated on a subset of run glasses analyzed by high-temperature vacuum manometry. Assuming that the solubility of H 2 O in mafic melt is relatively well known, estimates ofX    H  2   O    fluid       and         P    H  2   O    fluid$X_{{{\text{H}}_{2}}\text{O}}^{\text{fluid}}\ \text{and}\,\,\text{P}_{{{\text{H}}_{2}}\text{O}}^{\text{fluid}}$    in the saturating fluid were modeled, and by difference, values forXCO   2fluid       and         PCO   2fluid$X_{\text{C}{{\text{O}}_{2}}}^{\text{fluid}}\ \text{and}\,\,\text{P}_{\text{C}{{\text{O}}_{2}}}^{\text{fluid}}$   were obtained ( X  CO 2   ~0.5–0.9);  f  CO 2   could be then calculated from the fluid composition, temperature, and pressure.

american mineralogist

Constraints on deep, CO 2 -rich degassing at arc volcanoes from solubility experiments on hydrous basaltic andesite of Pavlof Volcano, Alaska Peninsula, at 300 to 1200 MPa