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The investigation of hydrous sulfate deposits and sulfate-cemented soils on the surface of Mars is one of the important topics in the recent scientific endeavor to retrieve detailed knowledge about the planetary water budget and surface weathering processes on our neighbor planet. Orbital visible/ near-IR spectra of the surface of Mars indicate kieserite, MgSO 4 ·H 2 O, as a dominant sulfate species at lower latitudes. However, given the Fe-rich composition of the martian surface, it is very probable that its actual composition lies at an intermediate value along the solid-solution series between the kieserite and szomolnokite (FeSO 4 ·H 2 O) end-members. Despite the known existence of significant lattice parameter changes and spectral band position shifts between the two pure end-members, no detailed crystal chemical and spectroscopic investigation along the entire kieserite–szomolnokite solid solution range has been done yet.

american mineralogist

Investigation of the kieserite–szomolnokite solid-solution series, (Mg,Fe)SO 4 ·H 2 O, with relevance to Mars: Crystal chemistry, FTIR, and Raman spectroscopy under ambient and martian temperature conditions