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We present experimental data on the diffusivity of Pb in CaTiO 3  perovskite, which is commonly used for dating kimberlites and carbonatites. Experiments were performed on oriented synthetic and natural CaTiO 3  single crystals. The Pb-source was either a laser deposited (Ca 0.83 Pb 0.07 )Ti 1.05 O 3  thin film or a (Ca 0.9 Pb 0.1 )TiO 3  powder reservoir. The crystals were annealed in a high-temperature furnace between 736 and 1135 °C and for durations from 2 to 283 h. The diffusion profiles were measured with Rutherford backscattering and time-of-flight secondary ion mass spectrometry in the depth-profiling mode. The concentration profiles measured on the same samples with the two analytical methods are in agreement. The measured concentration profiles show two regions—a steep gradient at the diffusion interface that transitions sharply (at ~50 to 150 nm from the surface) to a low concentration tail that penetrates deeper into the crystal. This diffusion behavior could be modeled best using diffusion coefficients that are a function of the Pb concentration, with a different set of diffusion coefficient for the high and the low concentration region of the profile, respectively. The diffusion coefficients extracted from the thin film and powder source experiments are similar within uncertainties. Pb diffuses slower at concentrations between 8.5 and 0.6 wt% and 1.6 to 2.6 log units faster below ~0.5 wt% Pb. Temperature dependency for each region is discussed in the text, and the Arrhenius relation for the fast diffusion regime that is most relevant for natural samples isD   Pb    fast    =  2.5  ×   10   −  13    ×  exp  ⁡   (   −  158   (   24   )   kJ/mol   /   R  T   )    m  2    /   s  .$$\begin{array}{} D_{\text{Pb}}^{\text{fast}}=2.5 \times 10^{-13}\times \exp \Big(-158\big(24\big)\text{kJ/mol}/RT\Big)m^2/s. \end{array} $$

american mineralogist

Lead diffusion in CaTiO 3 : A combined study using Rutherford backscattering and TOF-SIMS for depth profiling to reveal the role of lattice strain in diffusion processes