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Kinetics and reaction paths of Fe 3+  reduction by H 2  in high-Fe and low-H 2 O silicate melts have been investigated at 800 ℃. Time-series experiments were performed in cold-seal pressure vessels at 50 bars of pure H 2  using rapid-heating and rapid-quench strategies. Within the first minutes of the experiments, a fast partitioning of Na occurred between the gas and the melt due to the reducing conditions. Kinetically decoupled from the Na partitioning, the progression of a front of Fe 3+  reduction within the quenched melt was observed and was identified as a diffusion-limited process. The growth of the reduced layer is accompanied by an increase in concentration of OH-groups suggesting that reduction operates through proton incorporation within the melt. As this growth rate is slightly faster than predicted from the diffusion of molecular H 2 O, a different and mobile waterderived species seems likely. One possible mechanism is the reduction of Fe 3+  by the transport of molecular H 2 . As this process is limited by the flux of H 2 , it will depend on both diffusivity and solubility of H 2  in the melt. Alternatively, migration of protons (H + ) and electronic species within the melt could control the velocity of the reduction front. The increase in concentration of the reactionderived OH groups produces a water over saturation followed by partial dehydration of the melt. This dehydration leads to a change in the redox conditions within the gas that influences the Na partitioning between gas and melt.

Chemical transfer during redox exchanges between H 2 and Fe-bearing silicate melts