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There has been much interest in the chemistry of chain compounds of metal carboxylates with a lantern-like dinuclear structure, because they may have unique properties, such as gasocclusion.1–4 We reported that chain compounds of rhodium(II) carboxylates with N,N¢-bidentate ligands show adsorption properties for nitrogen gas.5–8 Analogous chain compounds of molybdenum(II) acetate can be expected to have an adsorption property for nitrogen gas. Recently, we synthesized a chain compound of molybdenum(II) acetate with 1,2-bis(4pyridyl)ethane (bpe) to make such a compound, because bpe has two binding sites with an ethane-type orientation.9 However, this compound did not show any adsorption property for N2, because of a non-porous structure in the crystals. In this study, we slightly modified the linking ligand to ethylene-type one, trans-1,2-bis(4-pyridyl)ethylene (bpel), to see any difference from those of [Mo2(CH3CO2)4(bpe)]n, because the corresponding rhodium(II) chain complex shows an adsorption property for N2. The crystal structure of catena(tetrakis(mX-ray Structure Analysis Online

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Synthesis and Crystal Structure of a Chain Complex of Molybdenum(II) Acetate and &lt;i&gt;trans&lt;/i&gt;-1,2-Bis(4-pyridyl)ethylene in Relation to the N&lt;sub&gt;2&lt;/sub&gt;-Adsorption Property