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分析試薬は可視化によって化学種やその濃度のような実験系の状態を把握する機能を有する検出対象物質に対する感度及び選択性が分析試薬の開発において強く求められているこのような条件を満たすために当研究室ではねじれ型分子内電荷移動TICT機構を用いた蛍光化学センサーを開発してきた本論文ではN-phenyl-9-anthacenecarboxamide9-AAを基本骨格としたTICT機構とその展開としてアルカリ土類金属または界面活性剤を検出するための9-AA誘導体について報告するAnalytical reagents have a function to recognize the state of an experimental system such as a species and its concentration by visualization. The sensitivity and selectivity are strongly requested in the development of a novel indicator. To fulfill these purposes, twisted intramolecular charge transfer (TICT) mechanisms have been employed for the development of novel fluorescent chemosensors in our study. In this paper, we report on the TICT mechanism of N-phenyl-9-anthacenecarboxamide (9-AA) as a fundamental structure and 9-AA derivatives to detect alkaline earth metal ions and a surfactant

Progress of the Fluorescent Chemosensor Based on the Control of Twisted Intramolecular Charge Transfer