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本研究では,大気汚染物質であるNO_2やSO_2を油絵具薄膜にさらすことにより,油絵具薄膜がどのような影響を受けるのかを,近赤外励起フーリエ変換ラマンを用い,油絵具薄膜の硬化及び劣化反応を官能基レベルで明らかにすることを試みた.その結果,NO_2ガス,SO_2ガスの油絵具の薄膜に対する全く異なる作用が官能基レベルで明らかにされ,油絵具はNO_2ガスとの反応性に富み,SO_2ガスとの反応性に乏しいということが分かった.The curing and degradation of oil paint thin films exposed with air pollutant gas i.e. NO_2 and SO_2 were investigated in terms of the functional goup level by NIR-excited fourier transform Raman spectroscopy. It was shown that the actions of NO_2 gas and SO_2 gas for paint films were clearly different between NO_2 and SO_2 for oil paints containing the inorganic and the organic pigments

Curing and degradation reactions of oil paints exposed to environmental pollutants (NO2 and SO2) as studied by NIR-excited Raman spectrometry