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The title compound, [Cu(C12H12N2S2)2]+(PF6)-, crystallizes in the monoclinic system, space group P21/c, with cell constants a = 10.1636(9)A, b = 15.0684(8)A, c = 18.7741(14)A, β = 90.747(7)° and Z = 4. The copper(I) ion is coordinated by four N atoms from two bidentate 6,6′-dimethylsulfanyl-2,2′-bipyridyl ligands. The CuN4 unit has a distorted tetrahedral geometry with the N-Cu-N angles ranging from 80.45(19)° to 139.8(2)°.

Crystal Structure of Bis(6,6'-dimethylsulfanyl-2,2'-bipyridyl)copper(I) Hexafluorophosphate