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The title compound, C7H6N4O2S, crystallizes in the monoclinic system, space group Cc, with cell constants a = 3.9122(9)A, b = 19.949(10)A, c = 11.323(3)A, β = 99.47(3)°, and Z = 4. The regioselective formation of this compound might be the result of steric and electronic considerations.

Synthesis and Solid-State Structure of 5-Methyl-2-(4-nitroimidazol-1-yl)thiazole