English (United Kingdom)

https://curated-unify.zendy.io/wp-json/zendy-region/v1/featured_content/oa?rat=en

https://curated-unify.zendy.io/wp-json/zendy-region/v1/highlighted_journal/

Zendy Open

Presents the pdf analysis as premium feature

PDF Analysis

Insights

Presents the summarisation as premium feature

Summarisation

Presents the keyphrase highlighting as premium feature

Keyphrase Highlighting

Presents the zaia usage as premium feature

ZAIA

Zendy Tools

Zendy Plus

Presents the access of premium content as premium feature

Premium Content

Single crystal X-ray analysis of the title compound, synthesized in the course of synthetic studies on taxinine (a congener of taxane diterpenes), has been performed to elucidate the relative stereochemistry at C(1), C(2), C(3), and C(8) atoms. The process of synthesis is shown in Fig, 1. Three isomers (76:17:7 in molar ratio) were obtained by the reaction of racemic aldehyde 1 and titanium enolate 2 in 46% yield. The acetal of the main product of these isomers 3 was replaced with triisopropylsilyl group (TIPS), and the crystal 4 was used for structure determination. Crystal and experimental data are listed in Table 1. The crystal decayed during the measurement. The intensity of 3 standard reflections measured every 100 reflections were decreased to 0.72 of the initial values. The decay correction was

analytical sciences

Crystal Structure of (5R*)-5-{(1S*)-[(1R*,2R*)-2-(Dibenzyloxymethyl)- 2-methyl-6-oxocyclohexyl]hydroxymethyl}-2,6,6-trimethyl- 3-[(triisopropylsilyl)oxy]-cyclohex-2-en-1-one