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In order to investigate the utility value of isotachophoresis(ITP) for partitioning of a nuclear fuel waste, a model solution was fractionated using a micro-preparative apparatus. The fractions of the separated zones were analyzed off-line by means of Particle Induced X-ray Emission (ITP-PIXE) and the migration order and the recovery was evaluated. Good separability was observed when a-hydroxyisobutyric acid was used as the complex-forming reagent, confirming the practical utility of isotachophoresis for the partitioning in principle.

STUDY OF ISOTACHOPHORETIC SEPARATION OF METAL IONS IN A WASTE GENERATED IN NUCLEAR FUEL CYCLE BY MEANS OF PARTICLE INDUCED X-RAY EMISSION