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Here, the combination of Nafion with microporous hollow carbon spheres (MHCS) is first proposed to fabricate a disposable metal-free electrode for heavy metal stripping sensing. The MHCS-Nafion composite film electrode is prepared by drop-casting a mixture of MHCS and Nafion onto the lab-made screen-printed carbon electrode (SPCE(*)). Results demonstrate that the interfusion of MHCS into Nafion offers enhanced performance for the electro-enrichment and stripping of lead and cadmium over the only Nafion film: 1) abundant MHCS immobilized on the electrode surface serve as effective nucleation sites for metal ion reduction; 2) the mixing of MHCS into Nafion enlarges the active surface of negative-charged Nafion for the electrostatic adsorption of metal cations. The proposed MHCS-Nafion/SPCE(*) provides linear responses for Pb(2+) and Cd(2+) in the range of 2 - 200 μg/L, with a detection limit of 1.37 and 1.63 μg/L, respectively. Practical applications of the sensor in water sample detection with good accuracy have also been confirmed.

Combination of Microporous Hollow Carbon Spheres and Nafion for the Individual Metal-free Stripping Detection of Pb2+ and Cd2+