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The electrical potential differences were measured at various points in an organic phase of a water-oil-water liquid membrane system in which self-oscillations of an electrical potential difference occurred across a three-phases-liquid membrane by using an H-shaped cell. The electrical potential difference oscillated in the direction through the two aqueous phases, but not in its vertical direction. The amplitude of the self-oscillation greatly changed around the place where the horizontal tube was connected to the vertical tube, which had no surfactant.

analytical sciences

Distribution of the Amplitude of the Self-Oscillation of the Electrical Potential Difference Observedinan Organic Phase of a Water-Oil-Water Liquid Membrane System