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Highly selective ligands for group 13 metal ions (Al 3+ , Ga 3+ and In 3+ ) have been successfully designed taking into consideration the bite size (O-O distance in the chelate ring) and the interligand contact in the complex. The complexation of Al 3+ was found to be under the effect of the interligand contact and that of In 3+ the bite size. The appropriate substituents were introduced to β-diketone type ligands to control the bite size and the volume of the ligand.

Molecular Design of Highly Selective Ligands for Group 13 Metals.