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Electrochemical analysis is considered to be applicable to the transport phenomena across a membrane which accompanies ionic reactions in the system where two solutions on both sides of the membrane are acidic and basic, respectively. Transport of halide ions across poly (vinylpyridine-co-styrene) membranes was analyzed by measuring the time dependence of the membrane resistance and bi-ionic potential. As a result, it becomes clear that poly (2-vinylpyridine-co-styrene) membranes are permselective for Cl- because HCl forms more easily pyridinium salt than HBr, and also that poly (4-vinylpyridine-co-styrene) membranes are permselective for Br- because the mobility of Br- is higher than that of Cl- in the membranes.

Electrochemical analysis of mass transport with ionic reactions in membranes. Ion selective transport across poly(vinylpyridine-co-styrene) membranes.