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The anionic graft-polymerization of propylene sulfide (PS) on the alkali-metallated nylon 6 fibers and the adsorption of heavy metal salts such as AgNO3 and HgCl2 on the grafted fibers were investigated.PS is easily graft-polymerized in the polar aprotic solvents such as dimethyl sulfoxide, dimethyl-formamide and etc., and is hardly graft-polymerized in the nonpolar solvent such as benzene. AgNO3 and HgCl2 are adsorbed by the poly (PS) graft-chains of the grafted fibers. Application of Langmuir's equation to the adsorption of AgNO3 shows that the amount of saturated adsorption per repeating unit of poly (PS) is 0.50_??_0.54 mol.

ANIONIC GRAFT-POLYMERIZATION OF PROPYLENE SULFIDE ON NYLON 6 FIBERS AND ADSORPTION OF HEAVY METAL SALTS ON THE GRAFTED FIBERS