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Synthesis of Polyimides derived from 2,6-diamino-4-methyl-1,3,5-triazine
Author(s) -
Rana R. Hamza
Publication year - 2016
Publication title -
baghdad science journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.167
H-Index - 6
eISSN - 2411-7986
pISSN - 2078-8665
DOI - 10.21123/bsj.2016.13.2.2ncc.0196
Subject(s) - triazine , chemistry , chloride , amine gas treating , condensation , benzoyl chloride , organic chemistry , polymer , proton nmr , polymer chemistry , medicinal chemistry , nuclear chemistry , thermodynamics , physics
This work included synthesis of several new polymers of polyacryloyl chloride in two steps . The first step the included the reaction of N-( sub. or un sub. benzoyl and sub. or un sub. acetyl ) amidyl sub. 2,6diamino -4-methyl-1,3,5-triazine (1-5) by condensation of many substituted acid chlorides with 2,6diamino -4methyl-1,3,5-triazine . While the second step included the reaction of polyacryloyl chloride with the produced compounds (1-5) in step (1) in the presence amount triethyl amine (Et3N) to obtain new polyimides (6-10). The prepared compounds were characterized by UV. , FT-IR, and some of them by 1 H-NMR and 13 CNMR spectroscopy.

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