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Ca11x/2Sr11x/2SiO4:xEu (x = 0.1­0.9) phosphors were synthesized using propylene glycol-modified silane (PGMS), and their luminescence properties were studied as a function of Eu concentration. The Ca11x/2Sr11x/2SiO4:xEu phosphors showed strong orange-red or red emissions. The wavelength at the maximum emission intensity shifted from 610 to 639 nm as Eu concentration increased from x = 0.1 to x = 0.7. The origin of the red emission was discussed in terms of Eu2+ substitution at smaller Ca (n) sites.

journal of the ceramic society of japan

Effect of Eu&lt;sup&gt;2+&lt;/sup&gt; concentration on the photoluminescence properties of red-emitting CaSrSiO&lt;sub&gt;4&lt;/sub&gt;:Eu&lt;sup&gt;2+&lt;/sup&gt; phosphors