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The solid state chemistry of mixed-metal oxides containing rare earths (4f elements) and 4d or 5d transition elements has attracted a great deal of interest, because these materials adopt a diverse range of structures and show a wide range of electronic properties due to 4f and 4d (or 5d) electrons. We have focused our attention on the structural chemistry and magnetic properties of perovskite-type oxides with the general formula A(n)LnM(n-1)O(3n) (A = Ca, Sr, Ba; Ln = rare earths; M = Ru, Ir; n = 1-4). Their structures are controlled by changing the ratio of the Ln and M ions, and peculiar magnetic properties and magnetic structures have been investigated by magnetic susceptibility, specific heat and neutron diffraction measurements. (C) 2015 The Ceramic Society of Japan. All rights reserved

Diverse structures of mixed-metal oxides containing rare earths and their magnetic properties