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V2O5-TeO2 glasses containing more than 80mol% V2O5 were obtained by moderate quenching of melts with addition of Fe2O3. These glasses are semiconductive by the small polaron hopping mechanism. The hopping process has been concluded to be adiabatic for [V2O5]≥50mol%. Fe ions, as well as V ions, seem to contribute to the hopping conduction, as suggested for Fe2O3-V2O5-P2O5 glasses. Dc conductivity of the tellurite glasses was more than 1 order of magnitude higher than that of phosphate glasses for [V2O5]≥70mol%. However, conductivities of both glasses were in the same order for [V2O5]≅80mol%. Relatively low conductivity of the tellurite glasses containing about 80mol% V2O5 was attributed to the very low value of the fraction of reduced V ion.

nihon seramikkusu kyoukai gakujyutsu rombunshi/nippon seramikkusu kyōkai gakujutsu rombunshi

Electrical Conduction and Structure of Fe&lt;sub&gt;2&lt;/sub&gt;O&lt;sub&gt;3&lt;/sub&gt;-V&lt;sub&gt;2&lt;/sub&gt;O&lt;sub&gt;5&lt;/sub&gt;-TeO&lt;sub&gt;2&lt;/sub&gt; Glasses (Part 1)