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The crystal structure and lithium ion conductivity of La1/3-xLi3xTaO3 solid solutions with the A-site deficient perovskite structure have been studied. Single phase solid solutions were obtained in the range of x=0 to 1/6. Change from tetragonal to cubic structure and decrease in the lattice volume were observed with increasing the x value. The maximum conductivity obtained was 7×10-3S·-1 at x=0.06. The composition-dependence on the carrier concentration was calculated and compared with conductivity data.

nihon seramikkusu kyoukai gakujyutsu rombunshi/nippon seramikkusu kyōkai gakujutsu rombunshi

Crystal Structure and Lithium Ion Conductivity of A-Site Deficient Perovskites La&lt;sub&gt;1/3-&lt;i&gt;x&lt;/i&gt;&lt;/sub&gt;Li&lt;sub&gt;3&lt;i&gt;x&lt;/i&gt;&lt;/sub&gt;TaO&lt;sub&gt;3&lt;/sub&gt;