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Recently in this laboratory a novel series  of 2-[(3-substitutedimino)-1,2,4-dithiazolo]amino-11-(piperazin-1-yl)dibenzo [b,f][1,4]oxazepines [VIB(a-h)] was synthesized by the oxidative cyclisation of 2-[substituted-2,4-dithiobiureto]-11-(piperazin-1-yl) dibenzo [b,f] [1,4]oxazepines [VB(a-h)]  in chloroform medium by making the use of liquid bromine as oxidizing agent.  The products were characterized and justified on the basis of elemental analysis, chemical characteristics and spectral studies.

SYNTHESIS OF 2-[(3-SUBSTITUTEDIMINO)-1,2,4-DITHIAZOLO]AMINO-11-(PIPERAZIN-1-YL)DIBENZO [b,f][1,4]OXAZEPINES