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In this paper, a novel cobalt-free cathode of Ba0.5Sr0.5Fe0.8Mn0.2O3-α (BSFMn) and electrolyte of BaZr0.1Ce0.7Y0.2O3-α (BZCY) were prepared by nitrate citric acid method. A single cell of NiO-BZCY —BZCY—BSFMn was assembled by a simple and effective slurry spin coating method and its H2/air fuel cell performance was also tested. The BSFMn, BZCY and NiO-BZCY were analyzed by X-ray diffraction (XRD). And a single cell after testing was analyzed using scanning electron microscopy (SEM). The maximum output power densities of NiO-BZCY—BZCY—BSFMn were 216 mW·cm, 351 mW·cm and 500 mW·cm at 600 °C, 650 °C and 700 °C, respectively.

Synthesis, Characterization and Electrochemical Properties of a Novel Cobalt-Free Ba0.5Sr0.5Fe0.8Mn0.2O3-α Intermediate-Temperature Cathode Material