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In this paper we discuss the problem of discussing the transport and catalytic reaction kinetics at redox enzymes immobilized within an electronically conductive polymer matrix where the effect of inhibition is specifically considered in the rate equation. Here the reaction kinetics are not of the simple MichaelisMenten type. WE describe a mathematical procedure based on the recently developed technique developed by Akbari and Ganji which facilitates a full analytical solution of the boundary value problem which is valid over an extended substrate concentration range. Closed form expressions for both the substrate concentration in the film and the steady state amperometric current response are presented. 10 limiting kinetic cases are identified and discussed.

international journal of electrochemical science

Transport and kinetics in electrocatalytic thin film conducting polymer biosensors: bounded diffusion with Michaelis-Menten kinetics incorporating general inhibition effects