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The super-hydrophobic self-assembled monolayers (SAMs) were prepared by self-assembled and etching method on 6061 aluminum alloys. Its wettability, morphology, and chemical composition of SAMs were investigated by contact angle (CA), field-emission scanning electron microscopy (FESEM), Fourier transform infrared spectroscopy (FTIR), X-ray photoelectron spectroscopy (XPS), and energy dispersive spectroscopy (EDS). The corrosion resistances of SAMs were studied by potentiometric polarization and AC impedance in 3.5 wt.% NaCl solution. The result indicated that self-assembled film had super-hydrophobic properties when bis-(3-triethoxysilylpropyl)-tetrasulfide (BTESPT) volume was 0.10mol/L. Electrochemical properties testing showed that the film had better corrosion resistance, in which the corrosion current density was maintain 1.140 ×10 A/cm and AC impedance reached 2.30 ×10 Ω•cm. Therefore, the film has both superhydrophobic and corrosion resistance characteristics.

international journal of electrochemical science

Effect of bis-(3-triethoxysilylpropyl)-tetrasulfide on SuperHydrophobicity and Corrosion Resistance of Self-Assembled Monolayers on 6061 Aluminum Alloys