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In this study, BaCe0.9Tm0.1O3- was prepared via a sol-gel combustion method using cerium nitrate, thulium oxide and barium nitrate as raw materials. Subsequently, it was reacted with the binary KClNaCl salts to obtain BaCe0.9Tm0.1O3--KCl-NaCl composite electrolyte. The structure, morphology, conductivity and fuel cell performance of the obtained samples were investigated. SEM images showed that KCl-NaCl inorganic molten salts covered and filled in the areas between the BaCe0.9Tm0.1O3- particles. The highest power density and conductivity of BaCe0.9Tm0.1O3--KClNaCl were 244.4 mW·cm and 2.1×10 S·cm S·cm at 700 °C, respectively.

Characterization and Intermediate Temperature Solid Oxide Fuel Cell Performances of BaCe0.9Tm0.1O3-α-KCl-NaCl Composite Electrolyte