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An erbium-doped SrCeO3/SrZrO3 electrolyte was synthesized via a sol-gel method using zirconium nitrate, cerium nitrate, strontium nitrate, nitric acid, citric acid and erbium oxide as raw materials. And SrCe0.6Zr0.3Er0.1O3--molten carbonate composite electrolyte was obtained at a low synthesis temperature. The thermal gravimetry analysis-differential scanning calorimetry (TGA-DSC) was tested to determine the formation temperature of SrCeO3/SrZrO3 solid solution phase. The structure (X–ray diffractometer, XRD), morphology (scanning electron microscope, SEM), conductivities and H2/O2 fuel cells of SrCe0.6Zr0.3Er0.1O3- and SrCe0.6Zr0.3Er0.1O3--Na2CO3-Li2CO3 were studied at 400-600 °C. The highest power densities of SrCe0.6Zr0.3Er0.1O3- and SrCe0.6Zr0.3Er0.1O3--Na2CO3-Li2CO3 were 16.3 mW·cm and 247.5 mW·cm at 600 °C, respectively.

Synthesis and Electrochemical Properties of Intermediate Temperature SrCe0.6Zr0.3Er0.1O3-α-molten Carbonate Composite Electrolyte