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In this paper, Nd and Y double doped ZrO2-low melting point glass powder (ZYN-glass) composite electrolyte was synthesized by solid-state reaction after heating at 700 °C for 6 h. XRD and SEM techniques were used to analyze the phase structures and morphologies of ZYN-glass. The (log (T)) based on the operating temperature of ZYN-glass was studied by means of the AC impedance at 400– 800 °C. The ZYN-glass showed the highest conductivity of 4.3×10 S·cm at 800 °C. Oxygen concentration difference cell: air, Pd-Ag∣ZYN-glass∣Pd-Ag, O2 was constructed at 400–700 C. H2/O2 fuel cell: H2, Pd-Ag∣ZYN-glass∣Pd-Ag, O2 was also tested at 800 C.

Synthesis and Intermediate Temperature Electrical Properties of Zr0.84Y0.12Nd0.04O2-α-Low Melting Point Glass Powder Composite Electrolyte